Digital basics
Digital only knows on and off
Voltage for a digital signal is either near 5 V or near 0 V. Nothing in between counts. Engineers call these two states HIGH and LOW, and they stand for the binary digits 1 and 0.
Every message, photo, song, and video your devices exchange is built from long streams of these two states. That is the entire alphabet of digital electronics.
Why the format?
Receivers are listening
The receiver does not know when a new character will arrive; the signal could sit idle for milliseconds or hours. So UART wraps each byte in a frame with a built-in signal: a LOW start bit.
That falling edge is the beginning. It says "a character begins right now," and the receiver clocks out the next ten bit slots automatically. The HIGH stop bit at the end says "I'm done, line is idle again."
Letters ride as numbers
ASCII is just a lookup table
The wire cannot carry the letter 'A' directly. It can only carry HIGHs and LOWs. So the sender looks up 'A' in a table called ASCII and finds the number 65. In binary, that is 01000001.
Those eight bits travel down the wire. The receiver looks up 65 in the same table and gets the letter back. You will use this lookup yourself in Decode mode.